tert-butylmagnesium chloride (CAS# 677-22-5)
| Xeerarka Khatarta | R12 - Aad u guban kara R14/15 - R19 - Waxa laga yaabaa inay sameeyaan peroxides qarxa R22 - Waxyeelo leh haddii la liqo R34 - Waxay sababtaa gubashada R66 - Soo-gaadhista soo noqnoqda waxay keeni kartaa maqaarka engegan ama dillaac R67 - Uumiga wuxuu keeni karaa lulmo iyo dawakhaad R15 - Biyo la taabashadu waxay xoraysaa gaasas aad u guban kara R11 - Aad u guban kara R14 - Wuxuu si xun uga falceliyaa biyo R37 - Ka xanaajiso habka neefsashada R17 – Si kedis ah ayay hawada u gubanaysaa R40 - Caddayn xaddidan ee saamaynta kansarka |
| Sharaxaada Badbaadada | S9 - Ku hay weelka meel hawo fiican leh. S16 - Ka fogow ilaha dabka. S26 - Haddii ay dhacdo in indhaha la taabto, isla markiiba ku raaci biyo badan oo raadso talo caafimaad. S29 - Ha ku faaruqin biyo mareennada. S33 - Qaado tillaabooyin taxaddar leh oo ka hortagga dheecaannada taagan. S36/37/39 - Xidho dhar ilaalin ku haboon, galoofyada iyo ilaalinta indhaha/wejiga. S43 - Haddii ay dhacdo isticmaalka dabka… (waxaa jira nooca qalabka dab-damiska ee la isticmaalayo.) S45 - Haddii ay dhacdo shil ama haddii aad dareento xanuun, raadso talo caafimaad isla markiiba (tus calaamadda mar kasta oo ay suurtagal tahay.) |
| Aqoonsiga UN-ka | UN 3399 4.3/PG 1 |
| WGK Germany | 1 |
| FLUKA BRAND F CODES | 1-3-10 |
| Koodhka HS | 29319090 |
| Heerka khatarta | 4.3 |
| Kooxda Baakadaha | I |
Hordhac
barta dhalaalka -108 ℃ (Tetrahydrofuran)
Cufnaanta 0.931g/ml at 25 c
Dhibicda 34 °F
Xaaladaha kaydinta 2-8°C
Dareeraha Morfological
Midab cad oo bunni ilaa madaw ah
Biyuhu milmayn la'aanta khamriga iyo biyaha.
Xasaasiyadda Hawada & Qoyaanka xasaasiga ah
BRN 3535403
InChIKey ZDRJSYVHDMFHSC-UHFFFAOYSA-M
Diyaarinta
Diyaarinta tert-butyl magnesium chloride: Isticmaal warqad ciid ah si aad uga saarto filimka oksaydhka ee dusha sare ee fiilada magnesium oo jar jajabyo fiican. Miisaanka 3.6g (0.15 mol) ee chips magnesium, oo lagu daray weel afar luqun ah oo ay ku rakiban yihiin qalabka ilaalinta nitrogen, kiciya, kondeneriyaha reflux iyo maanka dhibicda cadaadiska joogtada ah (Tuubada qalajinta CaCl2 ayaa lagu rakibay dusha sare ee kondenseriyaha reflux tuubada), waxay soo galisay nitrogen dhalada falcelinta qiyaastii 10 min, ka saar hawada ku jirta weelka afarta luqun, ka dibna waxay hagaajisay heerka socodka nitrogen, oo si joogto ah soo galiyay nitrogen aad u yar habka falcelinta. 35 ml oo ah tetrahydrofuran la safeeyey ayaa lagu daraa weelka afarta luqun leh, ka dibna 13.9g (0.15 mol) oo ah tert-butyl chloride ayaa la miisaamay, qiyaastii 3.5g oo tert-butyl chloride ah ayaa marka hore lagu daraa weelka afarta luqun ah, inta soo hartayna waa la miisaamaa. 10.4g oo tert-butyl chloride ah ayaa lagu qasaa 150 ml oo la safeeyey tetrahydrofuran ka dibna lagu daray cadaadiska joogtada ah ee kala soocida. Ku dar hadhuudh yar oo iodine ah, wax yar oo kulul, qadar yar oo xumbo ah ayaa la soo saaraa, midabka iodine ayaa hoos u dhacaya, waxaa lagu talinayaa in la ilaaliyo nidaamka falcelinta wax yar ka dib marka falcelinta la bilaabo, ka dib markaad hoos u dhigto, walaaq 3 ~ 4 h. ilaa chips magnesium ay si buuxda u baaba'aan, oo muujinaya xal cawl.
macluumaadka badbaadada
Alaabada khatarta ah f, c, f
Koodhka qaybta khatarta 12-14/15-19-22-34-66-67-15-11-14-37-17-40
Tilmaamaha badbaadada 9-16-26-29-33-36/37/39-43-45
Gaadiidka badeecooyinka khatarta ah lambarka UN 3399 4.3/PG 1
WGK Germany 1
F 1-3-10
Heerka Hazard 4.3
Kooxda xirxiran I
Koodhka kastamka 29319090
