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Benzidine (CAS#92-87-5)

Hantida Kiimikada:

Qaanuunka molecular C12H12N2
Molar Mass 184.24
Cufnaanta 1.25
Meesha dhalaalaysa 127-128°C
Boling Point 402°C
Barta Fiishka 11°C
Biyuhu milmayn Si yar u milma. <0.1 g/100 ml at 22ºC
Solubility Ku milmay ethanol (US EPA, 1985) iyo ether (1 g/50 mL) (Windholz et al., 1983)
Uumiga Uumiga Iyada oo ku saleysan qiimaha cufnaanta uumiga gaarka ah ee 6.36 (Sims et al., 1988), cadaadiska uumiga ayaa la xisaabiyay inuu noqdo 0.83 at 20 °C.
Muuqashada nadiif ah
Midabka Grayish-jaalle, budada crystalline; crystals cad ama sltlyreddish, budo
Xadka Muujinta Sababtoo ah waa kansar oo si diyaar ah looga nuugo maqaarka, ma jiro TLV oo loo qoondeeyay. Soo-gaadhista waa in ay ahaataa ugu yaraan. Kansarka (O
Merck 13,1077
BRN 742770
pKa 4.66 ( saacada 30 ℃)
Xaalada Kaydinta 2-8°C
Xasilooni Deggan guban kara Aan ku habboonayn walxaha oksaydhaynta ee xooggan.
Tusmada Dib-u-celinta 1.6266 (qiyaas)
Tilmaamaha Jirka iyo Kiimikada Budada crystalline cad ama guduudan. Dhibicda dhalaalka 125 ℃, barta karkarinta 400 ℃, (98.7kPa), cufnaanta qaraabo 1.250(20/4 ℃), milmay ee ethanol karkaraya, acetic acid iyo milo hydrochloric acid, wax yar ku milmay ether, wax yar ku milmay biyo karkaraya, aad u yar ku milmay biyo qabow. Midabku wuxuu ku madoobaa hawada iyo iftiinka. Dib-u-hawlgalayaasha falanqaynta badanaa waa benzidine hydrochloride ama acetate oo leh milmayn sare, iyo sulfate waxaa badanaa loo isticmaalaa warshadaha. Benzidine acetate waa caddaan ama ku dhawaad ​​cad cad, oo ku milma biyaha, acetic acid iyo hydrochloric acid, oo loo isticmaalo tilmaame [36341-27-2]. benzidine hydrochloride [531-85-1]. Benzidine sulfate waa budo crystalline cad ama miisaan yar oo u eg crystal, milmay ee ether, aad u yar oo biyo ku milmay, milo acid iyo khamriga [21136-70-9].

Faahfaahinta Alaabta

Tags Product

Xeerarka Khatarta R45 – Waxa uu keeni karaa kansar
R22 - Waxyeelo leh haddii la liqo
R50/53 - Aad bay ugu suntan noolaha biyaha, waxay u keeni kartaa saameyn xun muddo dheer deegaanka biyaha.
R52/53 - Waxyeelo u leh noolaha biyaha, waxay u keeni kartaa saameyn xun muddo dheer deegaanka biyaha.
R39/23/24/25 -
R23/24/25 - Sunta neefsashada, taabashada maqaarka iyo haddii la liqo.
R11 - Aad u guban kara
R36/37/38 - Waxay ka xanaajisaa indhaha, habka neefsashada iyo maqaarka.
R20/21/22 - Waxyeelo xagga neefsashada, taabashada maqaarka iyo haddii la liqo.
R51/53 - Sun ku leh noolaha biyaha, waxay u keeni kartaa saameyn xun muddo dheer deegaanka biyaha.
R67 - Uumiga wuxuu keeni karaa lulmo iyo dawakhaad
Sharaxaada Badbaadada S53 - Iska ilaali soo-gaadhista - hel tilmaamo gaar ah kahor isticmaalka.
S45 - Haddii ay dhacdo shil ama haddii aad dareento xanuun, raadso talo caafimaad isla markiiba (tus calaamadda mar kasta oo ay suurtagal tahay.)
S60 - Maaddadan iyo weelkeeda waa in lagu tuuraa sida qashinka khatarta ah.
S61 - Iska ilaali in lagu sii daayo deegaanka. Tixraac tilmaamaha gaarka ah / xaashiyaha xogta badbaadada.
S36/37 - Xidho dhar difaac ku haboon iyo galoofyada.
S16 - Ka fogow ilaha dabka.
S7 - weelka si adag u xidh.
S36 - Xidho dhar ilaalin ku habboon.
S26 - Haddii ay dhacdo in indhaha la taabto, isla markiiba ku raaci biyo badan oo raadso talo caafimaad.
Aqoonsiga UN-ka UN 1885 6.1/PG 2
WGK Germany 3
RTECS DC9625000
FLUKA BRAND F CODES 8
Koodhka HS 29215900
Heerka khatarta 6.1 (a)
Kooxda Baakadaha II
Sunta LD50 afka ba'an ee jiirarka 214 mg/kg, jiirka 309 mg/kg (xigasho, RTECS, 1985).

 

Hordhac

Benzidine (sidoo kale loo yaqaan diphenylamine) waa iskudhis organic ah. Kuwa soo socdaa waa hordhac dabeecadeeda, isticmaalkeeda, hababka wax-soo-saarka iyo macluumaadka badbaadada:

 

Tayada:

- Muuqashada: Benzidine waa mid adag oo cad ama huruud ah.

- Solubility: oo aan lagu milmin biyaha, ku milma dareerayaasha organic sida khamriga, ethers, iwm.

- Astaanta: Waa koronto-dhal leh sifooyinka falcelinta beddelka elektrofiliga.

 

Isticmaal:

- Benzidine waxaa si weyn loogu isticmaalaa berrinkii synthesis organic. Waxa loo isticmaali karaa sidii alaab cayriin ah iyo dhex-dhexaadka synthetic ee kiimikooyinka sida dheeha, midabada, balaastikada, iwm.

 

Habka:

- Benzidine waxaa dhaqan ahaan loo diyaariyaa dinitrobiphenyl dhimista, baabi'inta shucaaca haloaniline, iwm.

- Hababka diyaarinta casriga ah waxaa ka mid ah isku dhafka organic ee amines caraf udgoon, sida falcelinta substrate diphenyl ether leh alkanes amino.

 

Macluumaadka Badbaadada:

- Benzidine waa sun waxayna u keeni kartaa xanaaq iyo dhaawac jidhka bini'aadamka.

- Marka la maaraynayo benzidine, waa in laga taxaddaraa si looga fogaado taabashada maqaarka iyo neefsashada, iyo qalabka ilaalinta sida galoofyada, muraayadaha difaaca, iyo maaskaro ilaalinta haddii loo baahdo.

- Marka benzidine ay taabato maqaarka ama indhaha, waa in isla markiiba lagu dhaqaa biyo badan.

- Markaad kaydinayso oo aad isticmaalayso benzidine, ka taxadar inaad iska ilaaliso xidhiidhka walxaha organic iyo oksidants si aad uga hortagto dab ama qarax.

 


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